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Singly hydrogen bonded supramolecular ligands for highly selective rhodium-catalyzed hydrogenation reactions

Singly hydrogen bonded supramolecular ligands for highly selective rhodium-catalyzed hydrogenation reactions,10.1002/anie.200806177,Angewandte Chemie-

Singly hydrogen bonded supramolecular ligands for highly selective rhodium-catalyzed hydrogenation reactions   (Citations: 13)
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H bonds make the catalysts! A single hydrogen bond between ligands coordinated to a rhodium center is critical for the formation of pure supramolecular catalysts for asymmetric hydrogenation reactions. The ester group of the amidite ligand (see scheme) also forms a hydrogen bond with the coordinated substrate. Use of the heterocomplex afforded the highest enantioselectivity reported to date for the hydrogenation of several ester substrates.
Journal: Angewandte Chemie-international Edition - ANGEW CHEM INT ED , vol. 48, no. 12, pp. 2162-2165, 2009
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