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Exceptional thermal stability and thermodynamic properties of lithium based metal–organic framework

Exceptional thermal stability and thermodynamic properties of lithium based metal–organic framework,10.1007/s10973-010-0880-z,Journal of Thermal Analy

Exceptional thermal stability and thermodynamic properties of lithium based metal–organic framework   (Citations: 2)
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A three-dimensional lithium-based metal–organic framework Li2(2,6-NDC) (2,6-NDC = 2,6-naphthalene dicarboxylate) has been synthesized solvothermally and characterized by X-ray powder diffraction, elemental analysis, FT-IR spectroscopy, thermogravimetry and mass spectrometer analysis (TG–MS). The framework has exceptional stability and is stable to 863 K. The thermal decomposition characteristic of this compound was investigated through the TG–MS from 293 to 1250 K. The molar heat capacity of the compound was measured by temperature modulated differential scanning calorimetry (TMDSC) over the temperature range from 195 to 670 K for the first time. The thermodynamic parameters such as entropy and enthalpy versus 298.15 K based on the above molar heat capacity were calculated.
Journal: Journal of Thermal Analysis and Calorimetry - J THERM ANAL CALORIM , vol. 103, no. 1, pp. 373-380, 2011
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    • ...Similar (2,6-NDC)-based microporous compounds involving Mg [20] and Li [24] have been reported...
    • ...Besides the fundamental and practical importance in compiling various thermodynamic parameters (here Cp,m, DH and DS) and their variation with temperature for the two compounds investigated in this study, we have compared the present values with those obtained by our group using the same experimental methods for three other MOFtype materials based on NDC and optionally DMF in their structure, namely Li2(2,6-NDC) [24], Li2(1,4-NDC)(DMF) ...

    Chun-Hong Jianget al. Determination of heat capacities and thermodynamic properties of two s...

    • ...[340342], and Mg- or Cu-based MOFs were characterized by Song et al...

    S. Materazziet al. Evolved Gas Analysis by Mass Spectrometry

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