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Keywords
(10)
Chemical Reactors
co2 capture
Fluid Dynamics
Fluidized Bed
Fluidized Bed Reactor
Mathematical Modelling
Model Combination
Reaction Rate
Residence Time
Residence Time Distribution
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Modelling of a fluidized bed carbonator reactor to capture CO 2 from a combustion flue gas
Modelling of a fluidized bed carbonator reactor to capture CO 2 from a combustion flue gas,10.1016/j.ces.2008.10.044,Chemical Engineering Science,M. A
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Modelling of a fluidized bed carbonator reactor to capture CO 2 from a combustion flue gas
(
Citations: 10
)
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M. Alonso
,
N. Rodríguez
,
G. Grasa
,
J. C. Abanades
In recent years several processes incorporating a carbonation–calcination loop in an interconnected
fluidized bed reactor
have been proposed as a way to capture CO2 from flue gases. This paper is a first approximation to the modelling of a
fluidized bed
carbonator reactor. In this reactor the flue gas comes into contact with an active bed composed of particles with very different activities, depending on their
residence time
in the bed and in the carbonation–calcination loop. The model combines the
residence time distribution
functions with existing knowledge about sorbent deactivation rates and sorbent reactivity. The
fluid dynamics
of the solids (CSTR) and gases (PF) in the carbonator are based on simple assumptions. The carbonation rates are modelled defining a characteristic time for the transition between a fast reaction regime to a regime with a zero reaction rate. On the basis of these assumptions the model is able to predict the
CO2 capture
efficiency for the flue gas depending on the operating and design conditions. Operating windows with high capture efficiencies are discussed, as well as those conditions where only modest capture efficiencies are possible.
Journal:
Chemical Engineering Science - CHEM ENG SCI
, vol. 64, no. 5, pp. 883-891, 2009
DOI:
10.1016/j.ces.2008.10.044
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References
(20)
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Citations: 84
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J. Carlos Abanades
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Journal:
Energy & Fuels - ENERG FUEL
, vol. 17, no. 2, pp. 308-315, 2003
Capture of CO2 from combustion gases in a fluidized bed of CaO
(
Citations: 68
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J. Carlos Abanades
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Journal:
Aiche Journal - AICHE J
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(
Citations: 45
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,
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,
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Journal:
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(
Citations: 31
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Journal:
Industrial & Engineering Chemistry Research - IND ENG CHEM RES
, vol. 44, no. 15, pp. 5608-5615, 2005
The reversibility of the reaction CaCO3 ⇄ CaO+CO2
(
Citations: 35
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Journal:
Journal of Applied Chemistry and Biotechnology
, vol. 23, no. 10, pp. 733-742, 2007
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Citations
(10)
Experimental validation of in situ CO 2 capture with CaO during the low temperature combustion of biomass in a fluidized bed reactor
(
Citations: 2
)
J. C. Abanades
,
M. Alonso
,
N. Rodriguez
Journal:
International Journal of Greenhouse Gas Control - INT J GREENH GAS CONTROL
, vol. 5, no. 3, pp. 512-520, 2011
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, vol. 10, no. 7, pp. 472-472, 2011
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(
Citations: 8
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Journal:
International Journal of Greenhouse Gas Control - INT J GREENH GAS CONTROL
, vol. 4, no. 5, pp. 776-784, 2010
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(
Citations: 7
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Average activity of CaO particles in a calcium looping system
(
Citations: 8
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Journal:
Chemical Engineering Journal - CHEM ENG J
, vol. 156, no. 2, pp. 388-394, 2010