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Measurement of the Thermodynamics of the Hydrated Dimer and Trimer of Sulfuric Acid

Measurement of the Thermodynamics of the Hydrated Dimer and Trimer of Sulfuric Acid,10.1021/jp062844w,Journal of Physical Chemistry A,D. R. Hanson,E.

Measurement of the Thermodynamics of the Hydrated Dimer and Trimer of Sulfuric Acid   (Citations: 18)
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Journal: Journal of Physical Chemistry A - J PHYS CHEM A , vol. 110, no. 31, pp. 9525-9528, 2006
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    • ...This is because pure sulfuric acid clusters are too volatile to explain the high cluster concentrations that we observe (Hanson and Lovejoy 2006)...

    Jingkun Jianget al. First Measurements of Neutral Atmospheric Cluster and 1–2 nm Particle ...

    • ...Observations show that sulfuric acid, together with water and other gas phase molecules play an important role in atmospheric nucleation [Lee et al., 2003; Kulmala et al., 2006] and these systems are also the basis of many theoretical nucleation works [Wyslouzil et al., 1991; Hanson and Lovejoy, 2006]...

    Martin B. Enghoffet al. Aerosol nucleation induced by a high energy particle beam

    • ...Laboratory studies [Hanson and Lovejoy, 2006] have shown that the Vehkamäki et al. [2002] model overpredicted the BHN rates by about three orders of magnitude at low T. A significant overprediction may mislead one to think that BHN can account for the observed new particle formation rates in the upper troposphere while in reality the observed Table 1. Six Nucleation Schemes and Corresponding Variables Controlling the Predicted ...
    • ...The kinetic binary homogeneous nucleation (KBHN) model [Yu, 2007, 2008], which is constrained by multiple independent laboratory data sets (including those of Hanson and Lovejoy [2006]), appears to be more accurate...
    • ...BHN rates based on the parameterization of Wexler et al. [1994] are even higher than those of CBHN [Vehkamäki et al., 2002], which are known to have already overpredicted BHN rates by around three orders of magnitude [Hanson and Lovejoy, 2006; Yu, 2007]...

    Fangqun Yuet al. Spatial distributions of particle number concentrations in the global ...

    • ...The significance of ion‐mediated (ion‐induced) nucleation has been actively debated in the literature [Kulmala et al., 2007; Iida et al., 2006] and has been supported based on studies of the sulfuric acid dimer and trimer by Hanson and Lovejoy [2006]...

    E. G. Gokenet al. Reactions of formic acid with protonated water clusters: Implications ...

    • ...For comparison, experimental results from Hanson and Eisele [2000] and Hanson and Lovejoy [2006], and the values predicted on the basis of the parameterization of Vehkama¨ki et al. [2002] are also given...
    • ...In Figure 2c, the data from Hanson and Lovejoy [2006] for [H2SO4 ]=1 0 7 cm 3 and RH = 50% are the calculated net steady state fluxes between the dimer andtrimer basedon measured equilibriumconstant...

    Fangqun Yu. Updated H2SO4-H2O binary homogeneous nucleation look-up tables

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