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Keywords
(10)
Aqueous Solution
capsicum annuum
Data Fitting
Gibbs Free Energy
Heavy Metal
Kinetic Model
Kinetics
Langmuir Isotherm
Thermodynamic Parameter
Second Order
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Adsorption Potential of Lead(II) Ions from Aqueous Solutions onto Capsicum annuum Seeds
Adsorption Potential of Lead(II) Ions from Aqueous Solutions onto Capsicum annuum Seeds,10.1080/01496390600956977,Separation Science and Technology,A.
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Adsorption Potential of Lead(II) Ions from Aqueous Solutions onto Capsicum annuum Seeds
(
Citations: 1
)
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A. Safa Özcan
,
Adnan Özcan
,
Sibel Tunali
,
Tamer Akar
,
Ismail Kiran
,
Tevfik Gedikbey
The purpose of this work was to evaluate the adsorption potential of
Capsicum annuum
seeds, in a batch system for the removal of lead(II) ions from aqueous solutions. The experimental results showed that this agricultural by‐product was effective in removing lead(II) ions. The FT‐IR analysis indicated that the mechanism involved in adsorption of lead(II) ions by seeds of C. annuum was mainly attributed to lead(II) binding of amino and hydroxyl groups. Adsorption equilibrium approached within 40 min. The adsorption data fitted well to the
Langmuir isotherm
model. The maximum adsorption capacity (qmax) was 1.87×10 mol g. Pseudo‐second‐order
kinetic model
was applicable to all the adsorption data over the entire time range. The thermodynamic parameters indicated that the adsorption process is spontaneous since
Gibbs free energy
values are negative, which are between −26.92 and −30.77 kJ mol at the temperature range of 20–50°C.
Journal:
Separation Science and Technology - SEPAR SCI TECHNOL
, vol. 42, no. 1, pp. 137-151, 2007
DOI:
10.1080/01496390600956977
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(1)
Metals and seeds: Biochemical and molecular implications and their significance for seed germination
(
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,
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