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Synthesis, structural investigation, thermal decomposition mechanism and sensitivity properties of an energetic compound [Cd(DAT) 6](ClO 4) 2 (DAT = 1,5-diaminotetrazole)

Synthesis, structural investigation, thermal decomposition mechanism and sensitivity properties of an energetic compound [Cd(DAT) 6](ClO 4) 2 (DAT = 1

Synthesis, structural investigation, thermal decomposition mechanism and sensitivity properties of an energetic compound [Cd(DAT) 6](ClO 4) 2 (DAT = 1,5-diaminotetrazole)   (Citations: 6)
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An energetic coordination compound [Cd(DAT)6](ClO4)2 has been synthesized by using 1,5-diaminotetrazole (DAT) as ligand and its structure has been characterized by applying X-ray single crystal diffraction, elemental analysis and FT-IR spectroscopy. The central cadmium(II) cation is coordinated by six N atoms from six DAT molecules to form a six-coordinated and distorted octahedral structure. Di-dimension layer structure was formed and the layers were linked together by the extensive intermolecular hydrogen bonds between DAT ligands and ClO4− anions. Thermal decomposition mechanism of the title compound was predicted based on DSC, TG-DTG and FT-IR analyses results. The kinetic parameters of the first exothermic process of the title compound were studied by applying the Kissinger's and Ozawa–Doyle's methods. Sensitivity tests reveal that the title compound has sensitive nature.
Journal: Journal of Hazardous Materials - J HAZARD MATER , vol. 160, no. 1, pp. 45-50, 2008
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