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Branch selective allylation of acetylacetone catalyzed by Water-soluble rhodium complex catalyst

Branch selective allylation of acetylacetone catalyzed by Water-soluble rhodium complex catalyst,10.1016/j.jorganchem.2010.10.037,Journal of Organomet

Branch selective allylation of acetylacetone catalyzed by Water-soluble rhodium complex catalyst  
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[RhCl(1,5-cod)]2/PTA is highly active branch-selective catalyst for C-allylation of acetylacetone by allylic carbonates in water/ethyl acetate biphasic system, where either crotyl or 1-methylallyl carbonates gives sterically congested branched allylation product, suggesting formation of a common allylrhodium intermediate.
Journal: Journal of Organometallic Chemistry - J ORGANOMET CHEM , vol. 696, no. 10, pp. 1927-1930, 2011
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