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Application of dimeric cyclopalladated complex of tribenzylamine as an efficient catalyst in the Heck cross-coupling reaction

Application of dimeric cyclopalladated complex of tribenzylamine as an efficient catalyst in the Heck cross-coupling reaction,10.1016/j.jorganchem.201

Application of dimeric cyclopalladated complex of tribenzylamine as an efficient catalyst in the Heck cross-coupling reaction  
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The activity of [Pd{C6H4(CH2N(CH2Ph)2)} (μ-Br)]2 complex was investigated in the Heck–Mizoroki C–C cross-coupling reaction. This complex is an active and efficient catalyst for the Heck reaction of aryl iodides, bromides and even chlorides and also arenesulfonyl chlorides. The cross-coupled products were produced in excellent yields in short reaction time using a catalytic amount of [Pd{C6H4(CH2N(CH2Ph)2) (μ-Br)]2 complex in NMP at 130°C.
Journal: Journal of Organometallic Chemistry - J ORGANOMET CHEM , vol. 696, no. 13, pp. 2669-2675, 2011
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