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Keywords
(11)
Amino Acid Composition
Coastal Upwelling
Indexation
n2 fixation
Nitrogen Isotopes
Ocean Drilling Program
Organic Matter
Spatial Variation
Surface Sediment
Amino Acid
Arabian Sea
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Influence of diagenesis on sedimentary δ 15N in the Arabian Sea over the last 130 kyr
Influence of diagenesis on sedimentary δ 15N in the Arabian Sea over the last 130 kyr,10.1016/j.margeo.2011.03.013,Marine Geology,Jürgen Möbius,Birgit
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Influence of diagenesis on sedimentary δ 15N in the Arabian Sea over the last 130 kyr
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Jürgen Möbius
,
Birgit Gaye
,
Niko Lahajnar
,
Enno Bahlmann
,
Kay-Christian Emeis
Sedimentary δ15N records are valuable archives of ocean history but they are often modified during early diagenesis. Here we quantify the effect of early diagenetic enrichment on sedimentary N-isotope composition in order to obtain the pristine signal of reactive N assimilated in the euphotic zone. This is possible by using paired data of δ15N and
amino acid composition
of sediment samples, which can be applied to estimate the degree of
organic matter
degradation. We determined δ15N and
amino acid composition
in coeval sediments from
Ocean Drilling Program
(ODP) Hole 772 B in the central
Arabian Sea
and from Hole 724 C situated on the Oman Margin in the western
Arabian Sea
coastal upwelling
area. The records span the last 130kyr and include two glacial–interglacial cycles. These new data are used in conjunction with data available for surface sediments that cover a wide range of
organic matter
degradation states, and with other cores from the northern and eastern
Arabian Sea
to explore spatial variations in the isotopic signal. In order to reconstruct pristine N values we apply the relationship between
organic matter
degradation and 15N enrichment in surface sediments to correct the core records for early diagenetic enrichment. Reconstructed δ15N values suggest a significant role of N2-fixation during glacial stages. An evaluation of two preservation indices based on
amino acid composition
(Reactivity Index, RI; Jennerjahn and Ittekkot, 1997; and the Degradation Index, DI; Dauwe et al., 1999) in both recent sediments and core samples suggests that the RI is more suitable than the DI in correcting
Arabian Sea
δ15N records for early diagenetic enrichment.
Journal:
Marine Geology - MAR GEOLOGY
, vol. 284, no. 1, pp. 127-138, 2011
DOI:
10.1016/j.margeo.2011.03.013
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