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Excess molar volumes of ternary liquid mixtures composed of 1, 4-dioxane, o-toluidine, and aromatic hydrocarbon at temperature of 308.15 K

Excess molar volumes of ternary liquid mixtures composed of 1, 4-dioxane, o-toluidine, and aromatic hydrocarbon at temperature of 308.15 K,10.1016/j.m

Excess molar volumes of ternary liquid mixtures composed of 1, 4-dioxane, o-toluidine, and aromatic hydrocarbon at temperature of 308.15 K  
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Excess molar volumes, VijkE, of 1,4-dioxane (i)+o-toluidine (j)+benzene or toluene or m- or p-xylene (k) ternary mixtures have been measured dilatometrically as a function of composition at 308.15K. The resulting VijkE data have been fitted to Redlich–Kister equation to evaluate ternary adjustable parameters and standard deviations σ(VijkE). The observed VijkE data have been analyzed in terms of (i) Graph theory; and (ii) Prigogine–Flory–Patterson theory. It has been observed that Graph theory correctly predicts the sign and magnitude of VijkE values.
Journal: Journal of Molecular Liquids - J MOL LIQ , vol. 158, no. 3, pp. 192-196, 2011
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