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Keywords
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Copper Oxide
Iron
Non Destructive Testing
Optical Spectroscopy
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Optical spectroscopy as a rapid and low-cost tool for the first-line analysis of glass artefacts: a step-by-step plan for Roman green glass
Optical spectroscopy as a rapid and low-cost tool for the first-line analysis of glass artefacts: a step-by-step plan for Roman green glass,10.1016/j.
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Optical spectroscopy as a rapid and low-cost tool for the first-line analysis of glass artefacts: a step-by-step plan for Roman green glass
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Wendy Meulebroeck
,
Peter Cosyns
,
Kitty Baert
,
Hilde Wouters
,
Simone Cagno
,
Koen Janssens
,
Herman Terryn
,
Karin Nys
,
Hugo Thienpont
Archaeometric research on glass artefacts is continuously evolving and is converging towards a multidisciplinary research domain where different types of techniques are applied depending on the questions asked and the circumstances involved. The technique described in this work is optical spectroscopy. The benefit of this technique being the possibility of building up a knowledge database for a large amount of material in a relatively
short period
of time and with a relatively limited budget. This is of particular interest for the investigation of extensive and/or unexplored glass collections where a first-line analysis of artefacts could facilitate the selection of material needing further and more detailed examination.This publication explores the extent to which
optical spectroscopy
can be used for a first-line analysis of green coloured glass artefacts from the Roman period. It is shown that the colour coordinates calculated from the measured transmission
spectrum
could reveal information about the fragment under study. In particular it is shown that 1) based on the position of the calculated colour values on the colour diagram (CIE1931) one could easily know whether the artefact was coloured using only
iron
or if
copper
oxides were also present. In the case of the artefact owing its colour solely to the presence of iron, the distance between the measured colour values and the colour diagram’s white point can roughly indicate the
iron
concentration of the sample; 2) artefacts that were fabricated under similar furnace conditions can also be identified on the colour diagram; 3) samples with identical compositions and fabrication conditions but with different sample thickness, gave rise to a variation in the colour coordinates, thus allowing
optical spectroscopy
to help identify fragments which might belong to the same object.
Journal:
Journal of Archaeological Science - J ARCHAEOL SCI
, vol. 38, no. 9, pp. 2387-2398, 2011
DOI:
10.1016/j.jas.2011.04.023
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