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A new BEDT-TTF-based organic metal with an anionic weak acceptor 2-sulfo-1,4-benzoquinone

A new BEDT-TTF-based organic metal with an anionic weak acceptor 2-sulfo-1,4-benzoquinone,10.1016/j.synthmet.2011.08.045,Lancet,Hiroki Akutsu,Yuka Mar

A new BEDT-TTF-based organic metal with an anionic weak acceptor 2-sulfo-1,4-benzoquinone  
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An anionic weak acceptor, 2-sulfo-1,4-benzoquinone, has provided a new BEDT-TTF (bis(ethylenedithio)tetrathiafulvalene) salt (BEDT-TTF)2(2-sulfo-1,4-benzoquinone)·H2O. Single crystal X-ray analysis indicates that the unit cell has two crystallographically independent donor layers, one of which has a β″-type packing motif and the other being disordered. Population analysis and SQUID magnetometry suggests that non-β″-layer has an α‴-type packing motif. The dual-layered salt shows metallic behavior with a metal–insulator transition at 90K.
Journal: Lancet , vol. 161, no. 21, pp. 2339-2343, 2011
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